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research article

Sample restriction using magnetic field gradients in high-resolution solid-state NMR

Charmont, P
•
Lesage, A
•
Steuernagel, S
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2000
Journal of Magnetic Resonance

Many solid-state NMR experiments are sensitive to inhomogeneity in the radiofrequency field. We propose a method to restrict the sample volume, in magic angle spinning experiments, using a static magnetic field gradient and a selective pulse. The position of the gradient is calculated for our experimental configuration and we have simulated the effects of selective pulses to determine the excited volume. The resulting sequences are applied to a sample of sodium acetate using frequency-switched Lee-Goldburg proton-proton homonuclear dipolar decoupling. A gain of a factor of 2 on the carbon resolution is experimentally observed. (C) 2000 Academic Press.

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Type
research article
DOI
10.1006/jmre.2000.2117
Web of Science ID

WOS:000088867100020

Author(s)
Charmont, P
Lesage, A
Steuernagel, S
Engelke, F
Emsley, L  
Date Issued

2000

Publisher

Academic Press Inc

Published in
Journal of Magnetic Resonance
Volume

145

Issue

2

Start page

334

End page

339

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LRM  
Available on Infoscience
January 8, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/110137
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