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  4. Correlation of fast and slow chemical shift spinning sideband patterns under fast magic-angle spinning
 
research article

Correlation of fast and slow chemical shift spinning sideband patterns under fast magic-angle spinning

Elena, B
•
Hediger, S
•
Emsley, L  
2003
Journal of Magnetic Resonance

A new two-dimensional solid-state NMR experiment, which correlates slow and fast chemical shift anisotropy sideband patterns is proposed. The experiment, dubbed ROSES, is performed under fast magic-angle spinning and leads to an isotropic spectrum in the directly detected omega(2) dimension. In the evolution dimension omega(1), the isotropic chemical shift is reduced by a factor S, and spinning sidebands are observed spaced by a scaled effective spinning speed omega(R)/S. These spinning sidebands patterns are not identical to those observed with standard slow magic-angle spinning experiments. Chemical shift anisotropy parameters can be accurately extracted with standard methods from these spinning sideband patterns. The experiment is demonstrated with carbon-13 experiments on powdered samples of a dipeptide and a cyclic undecapeptide, cyclosporin-A. (C) 2002 Elsevier Science (USA). All rights reserved.

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Type
research article
DOI
10.1016/S1090-7807(02)00037-X
Web of Science ID

WOS:000181638500006

Author(s)
Elena, B
Hediger, S
Emsley, L  
Date Issued

2003

Publisher

Academic Press Inc - Elsevier Science

Published in
Journal of Magnetic Resonance
Volume

160

Issue

1

Start page

40

End page

46

Subjects

solid-state NMR

•

MAS

•

chemical shift anisotropy

•

scaling

•

spinning sidebands

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LRM  
Available on Infoscience
January 8, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/110114
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