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research article

Resonator with reduced sample heating and increased homogeneity for solid-state NMR

Krahn, Alexander
•
Priller, Uwe
•
Emsley, Lyndon  
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2008
Journal of Magnetic Resonance

In the application of solid-state NMR to many systems, the presence of radiofrequency (rf) electric fields inside classical solenoidal coils causes heating of lossy samples. in particular, this is critical for proteins in ionic buffers. Rf sample heating increases proportional to frequency which may result in the need to reduce the rf pulse power to prevent partial or total sample deterioration. In the present paper, we propose a multifrequency-tunable NMR resonator where the sample is electrically shielded from the NMR coil by a conductive sheet that increases the magneto-electric ratio. Expressions for the B-1 efficiency as function of magnetic and electric filling factors are derived that allow a direct comparison of different resonators. Rf efficiency, homogeneity, signal-to-noise, and rf sample heating are compared. NMR spectra at 700 MHz on ethylene glycol, glycine, and a model protein were acquired to compare the resonators under realistic experimental conditions. (C) 2007 Elsevier Inc. All rights reserved.

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Type
research article
DOI
10.1016/j.jmr.2007.12.004
Web of Science ID

WOS:000253500700009

Author(s)
Krahn, Alexander
Priller, Uwe
Emsley, Lyndon  
Engelke, Frank
Date Issued

2008

Publisher

Academic Press Inc - Elsevier Science

Published in
Journal of Magnetic Resonance
Volume

191

Issue

1

Start page

78

End page

92

Subjects

rf heating of samples

•

numerical electromagnetic field simulation

•

NMR coils

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LRM  
Available on Infoscience
January 8, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/110056
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