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research article

Optical properties of BiTeBr and BiTeCl

Akrap, Ana
•
Teyssier, Jeremie
•
Magrez, Arnaud
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2014
Physical Review B

We present a comparative study of the optical properties-reflectance, transmission, and optical conductivity- and Raman spectra of two layered bismuth-tellurohalides BiTeBr and BiTeCl at 300 and 5 K, for light polarized in the a-b planes. Despite different space groups, the optical properties of the two compounds are very similar. Both materials are doped semiconductors, with the absorption edge above the optical gap which is lower in BiTeBr (0.62 eV) than in BiTeCl (0.77 eV). The same Rashba splitting is observed in the two materials. A non-Drude free carrier contribution in the optical conductivity, as well as three Raman and two infrared phonon modes, are observed in each compound. There is a dramatic difference in the highest infrared phonon intensity for the two compounds, and a difference in the doping levels. Aspects of the strong electron-phonon interaction are identified. Several interband transitions are assigned, among them the low-lying absorption beta which has the same value 0.25 eV in both compounds, and is caused by the Rashba spin splitting of the conduction band. An additional weak transition is found in BiTeCl, caused by the lower crystal symmetry.

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Type
research article
DOI
10.1103/PhysRevB.90.035201
Web of Science ID

WOS:000338650600002

Author(s)
Akrap, Ana
Teyssier, Jeremie
Magrez, Arnaud
Bugnon, Philippe
Berger, Helmuth  
Kuzmenko, Alexey B.
Van Der Marel, Dirk
Date Issued

2014

Publisher

Amer Physical Soc

Published in
Physical Review B
Volume

90

Issue

3

Article Number

035201

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSE  
Available on Infoscience
August 29, 2014
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/106330
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