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  4. Influence of Y and La Additions on Grain Growth and the Grain-Boundary Character Distribution of Alumina
 
research article

Influence of Y and La Additions on Grain Growth and the Grain-Boundary Character Distribution of Alumina

Bojarski, Stephanie A.
•
Stuer, Michael  
•
Zhao, Zhe
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2014
Journal Of The American Ceramic Society

Grain-boundary character distributions (GBCDs) were determined for spark plasma sintered Y- and La-doped aluminas prepared at temperatures between 1450 degrees C and 1600 degrees C. La doping leads to grain boundaries that adopt (0001) orientations 3.7 times more frequently than expected in a random distribution, whereas the Y-doped microstructures are more equiaxed. At 1500 degrees C, some of the boundaries in the Y-doped samples transform to a higher mobility complexion; in this microstructure, the {01 (1) over bar2} grain-boundary plane is 1.3 times more likely to occur than expected in a random distribution. After the fast-growing grains impinge, the dominant plane becomes {11 (2) over bar0} and these boundaries have areas that are 1.2 times more likely to occur than expected in a random distribution. The grain-boundary planes in the Y- and La-codoped samples preferred (0001) and {01 (1) over bar2>} orientations, combining the characteristics of the singly doped samples. Grain boundaries with a 60 degrees misorientation about [0001] were up to six times more common than random in the Y-doped samples. The preference for (0001) oriented grain-boundary planes in the La-doped sample persisted at all specific misorientations.

  • Details
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Type
research article
DOI
10.1111/jace.12669
Web of Science ID

WOS:000330684200043

Author(s)
Bojarski, Stephanie A.
Stuer, Michael  
Zhao, Zhe
Bowen, Paul  
Rohrer, Gregory S.
Date Issued

2014

Publisher

Wiley-Blackwell

Published in
Journal Of The American Ceramic Society
Volume

97

Issue

2

Start page

622

End page

630

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LTP  
Available on Infoscience
April 2, 2014
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/102447
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