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Metal‐Mediated Synthesis of a Mixed Arduengo‐Fischer Carbodicarbene Ligand

Kooij, Bastiaan  
•
Chen, Damien Wen  
•
Fadaei Tirani, Farzaneh  
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June 10, 2024
Angewandte Chemie International Edition

Carbodicarbenes are strong C‐donor ligands, which have found numerous applications in organometallic and main group element chemistry. Herein, we report a structurally distinct carbodicarbene ligand, which is formed by dinitrogenative coupling of a Fischer carbene complex with an N‐heterocyclic diazoolefin. The resulting carbonyl complex serves as a stable source for the mixed Arduengo‐Fischer carbodicarbene ligand. Facile ligand transfer reactions were demonstrated to occur with gold(I), copper(I), palladium(II), and rhodium(I) complexes.

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Angew Chem Int Ed - 2024 - Kooij - Metal‐Mediated Synthesis of a Mixed Arduengo‐Fischer Carbodicarbene Ligand.pdf

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