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research article

Flash Melting Amorphous Ice

Mowry, Nathan Junior  
•
Krüger, Constantin Richard  
•
Bongiovanni, Gabriele  
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May 9, 2024
The Journal of Chemical Physics

Water can be vitrified if it is cooled at high rates, which makes it possible to outrun crystallization in so-called no man’s land, a range of deeply supercooled temperatures where water crystallizes rapidly. Here, we study the reverse process in pure water samples by flash melting amorphous ice with microsecond laser pulses. Time-resolved electron diffraction reveals that the sample transiently crystallizes despite a heating rate of more than 5 × 106 K/s, even though under the same conditions, vitrification can be achieved with a similar cooling rate of 107 K/s. Moreover, we observe different crystallization kinetics for amorphous solid water and hyperquenched glassy water. These experiments open up new avenues for elucidating the crystallization mechanism of water and studying its dynamics in no man’s land. They also add important insights into the laser melting and revitrification processes that are integral to the emerging field of microsecond time-resolved cryo-electron microscopy.

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Type
research article
DOI
10.1063/5.0202948
Author(s)
Mowry, Nathan Junior  
Krüger, Constantin Richard  
Bongiovanni, Gabriele  
Drabbels, Marcel  
Lorenz, Ulrich  
Date Issued

2024-05-09

Published in
The Journal of Chemical Physics
Volume

160

Issue

184502

Note

This paper is part of the JCP Special Topic on Water: Molecular Origins of its Anomalies

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LND  
Available on Infoscience
May 13, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/207873
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