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research article

Disorder-Driven Spin-Orbital Liquid Behavior in the Ba3XSb2O9 Materials

Smerald, Andrew  
•
Mila, Frederic  
2015
Physical Review Letters

Recent experiments on the Ba3XSb2O9 family have revealed materials that potentially realize spin-and spin-orbital liquid physics. However, the lattice structure of these materials is complicated due to the presence of charged X2+-Sb5+ dumbbells, with two possible orientations. To model the lattice structure, we consider a frustrated model of charged dumbbells on the triangular lattice, with long-range Coulomb interactions. We study this model using Monte Carlo simulation, and find a freezing temperature, T-frz, at which the simulated structure factor matches well to low-temperature x-ray diffraction data for Ba3CuSb2O9. At T = T-frz we find a complicated "branching" structure of superexchange-linked X2+ clusters, which form a fractal pattern with fractal dimension d(f) = 1.90. We show that this gives a natural explanation for the presence of orphan spins. Finally we provide a plausible mechanism by which such dumbbell disorder can promote a spin-orbital resonant state with delocalized orphan spins.

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Type
research article
DOI
10.1103/PhysRevLett.115.147202
Web of Science ID

WOS:000362096600009

Author(s)
Smerald, Andrew  
Mila, Frederic  
Date Issued

2015

Published in
Physical Review Letters
Volume

115

Issue

14

Article Number

147202

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
CTMC  
Available on Infoscience
December 2, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/121135
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