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  4. Effect of annealing and silylation on the strength of melt-spun Ni-Mn-Ga fibres and their adhesion to epoxy
 
research article

Effect of annealing and silylation on the strength of melt-spun Ni-Mn-Ga fibres and their adhesion to epoxy

Glock, Susanne  
•
Sparnins, Edgars  
•
Leterrier, Yves  
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2014
International Journal of Adhesion and Adhesives

Single crystals of ferromagnetic Ni-Mn-Ga shape memory alloys show magnetic-field and stress induced twinning, leading to shape memory. Adaptive composites can thus be produced by embedding single crystalline particles or bamboo-structured Ni-Mn-Ga fibres into a polymer matrix. To guarantee a durable performance of these composites, adhesion between reinforcement phase and matrix should be quantified and optimised. The influence of annealing and surface treatment with an aminosilane of melt-spun Ni-Mn-Ga fibres on their strength and adhesion to an epoxy matrix was investigated using single fibre tension and fragmentation tests. Annealing of the melt-spun Ni-Mn-Ga fibres changed the surface from a "pimpled" to a smooth microstructure. This resulted in a reduced adhesion of the annealed fibres in comparison to the as-spun fibres embedded in an epoxy matrix. As-spun fibres exhibited an interfacial shear strength (IFSS) comparable to the shear strength of the epoxy matrix so that the silylation did not change the adhesion significantly. For the annealed fibres, the silane treatment improved the IFSS by 67%. Furthermore, the silylation increased the fracture strength of the Ni-Mn-Ga fibres due to surface flaw healing or forming of a protective surface coating. (C) 2014 Elsevier Ltd. All rights reserved.

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Type
research article
DOI
10.1016/j.ijadhadh.2014.08.002
Web of Science ID

WOS:000344430200012

Author(s)
Glock, Susanne  
Sparnins, Edgars  
Leterrier, Yves  
Michaud, Veronique  
Date Issued

2014

Published in
International Journal of Adhesion and Adhesives
Volume

55

Start page

89

End page

94

Subjects

Epoxides

•

Fibres

•

Silanisation

•

Interfaces

•

Magnetic shape memory alloy

•

Fragmentation test

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LTC  
LPAC  
FunderGrant Number

FNS

National Research Programme NRP 62 n°406240-126120

Available on Infoscience
December 30, 2014
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/109641
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