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  4. A Structure-Activity Study of Nickel NNN Pincer Complexes for Alkyl-Alkyl Kumada and Suzuki-Miyaura Coupling Reactions
 
research article

A Structure-Activity Study of Nickel NNN Pincer Complexes for Alkyl-Alkyl Kumada and Suzuki-Miyaura Coupling Reactions

Di Franco, Thomas  
•
Stojanovic, Marko
•
Keller, Sebastien Carlos
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2016
Helvetica Chimica Acta

A new series of Ni NNN pincer complexes were synthesized and characterized. The main difference among these complexes is the substituents on the side arm amino group(s). No major structural difference was found except for the C-N-C angle of the various substituents and the 'pseudo bite angle' of the complexes. Four new complexes were efficient for the alkyl-alkyl Kumada reaction of primary alkyl halides, and among them, one complex was also efficient with secondary alkyl halides. The influence of the substituents on the catalytic performance of the Ni complexes in alkyl-alkyl Kumada and Suzuki-Miyaura cross-coupling reactions was systematically investigated. No correlation was found between the catalytic activity and the key structural parameters (C-N-C angle and 'pseudo bite angle'), redox properties or Lewis acidity of the complexes.

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Type
research article
DOI
10.1002/hlca.201600165
Web of Science ID

WOS:000388726500002

Author(s)
Di Franco, Thomas  
Stojanovic, Marko
Keller, Sebastien Carlos
Scopelliti, Rosario  
Hu, Xile  
Date Issued

2016

Publisher

Wiley-Blackwell

Published in
Helvetica Chimica Acta
Volume

99

Issue

11

Start page

830

End page

847

Subjects

Nickel

•

Pincer ligands

•

Cross-coupling reaction

•

Alkyl halides

•

Structure-activity study

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSCI  
Available on Infoscience
January 24, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/133677
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