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  4. The isotopic record of Northern Hemisphere atmospheric carbon monoxide since 1950: Implications for the CO budget
 
research article

The isotopic record of Northern Hemisphere atmospheric carbon monoxide since 1950: Implications for the CO budget

Wang, Z.
•
Chappellaz, J.
•
Martinerie, P.
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May 16, 2012
Atmospheric Chemistry And Physics

We present a 60-year record of the stable isotopes of atmospheric carbon monoxide (CO) from firn air samples collected under the framework of the North Greenland Eemian Ice Drilling (NEEM) project. CO concentration, δ 13C, and δ 18O of CO were measured by gas chromatography/isotope ratio mass spectrometry (gc-IRMS) from trapped gases in the firn. We applied LGGE-GIPSA firn air models (Witrant et al., 2011) to correlate gas age with firn air depth and then reconstructed the trend of atmospheric CO and its stable isotopic composition at high northern latitudes since 1950. The most probable firn air model scenarios show that δ 13C decreased slightly from-25.8% in 1950 to-26.4% in 2000, then decreased more significantly to-27.2% in 2008. δ18O decreased more regularly from 9.8% in 1950 to 7.1% in 2008. Those same scenarios show CO concentration increased gradually from 1950 and peaked in the late 1970s, followed by a gradual decrease to present day values (Petrenko et al., 2012). Results from an isotope mass balance model indicate that a slight increase, followed by a large reduction, in CO derived from fossil fuel combustion has occurred since 1950. The reduction of CO emission from fossil fuel combustion after the mid-1970s is the most plausible mechanism for the drop of CO concentration during this time. Fossil fuel CO emissions decreased as a result of the implementation of catalytic converters and the relative growth of diesel engines, in spite of the global vehicle fleet size having grown several fold over the same time period. © 2012 Author(s).

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Type
research article
DOI
10.5194/acp-12-4365-2012
Web of Science ID

WOS:000304672000001

Author(s)
Wang, Z.
Chappellaz, J.
Martinerie, P.
Park, K.
Petrenko, V.
Witrant, E.
Emmons, L. K.
Blunier, T.
Brenninkmeijer, C. a. M.
Mak, J. E.
Date Issued

2012-05-16

Publisher

Copernicus GmbH

Published in
Atmospheric Chemistry And Physics
Volume

12

Issue

10

Start page

4365

End page

4377

Subjects

air sampling

•

atmospheric chemistry

•

carbon emission

•

carbon monoxide

•

concentration (composition)

•

emission control

•

fossil fuel

•

isotopic composition

•

mass balance

•

Northern Hemisphere

•

stable isotope

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
SENSE  
Available on Infoscience
November 23, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/192710
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