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  4. Oxygen-17 dynamic nuclear polarisation enhanced solid-state NMR spectroscopy at 18.8 T
 
research article

Oxygen-17 dynamic nuclear polarisation enhanced solid-state NMR spectroscopy at 18.8 T

Brownbill, Nick J.
•
Gajan, David
•
Lesage, Anne
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2017
Chemical Communications (ChemComm)

We report O-17 dynamic nuclear polarisation (DNP) enhanced solid-state NMR experiments at 18.8 T. Several formulations were investigated on the Mg(OH)(2) compound. A signal enhancement factor of 17 could be obtained when the solid particles were incorporated into a glassy o-terphenyl matrix doped with BDPA using the Overhauser polarisation transfer scheme whilst the cross effect mechanism enabled by TEKPol yielded a slightly lower enhancement but more time efficient data acquisition.

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Type
research article
DOI
10.1039/c6cc09743j
Web of Science ID

WOS:000395873100007

Author(s)
Brownbill, Nick J.
Gajan, David
Lesage, Anne
Emsley, Lyndon  
Blanc, Frederic
Date Issued

2017

Publisher

Royal Society of Chemistry

Published in
Chemical Communications (ChemComm)
Volume

53

Issue

17

Start page

2563

End page

2566

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LRM  
Available on Infoscience
May 1, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/136710
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