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research article

Cold-Field Switching in PVDF-TrFE Ferroelectric Polymer Nanomesas

Stolichnov, Igor  
•
Maksymovych, Peter
•
Mikheev, Evgeny
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2012
Physical Review Letters

Polarization reversal in ferroelectric nanomesas of polyvinylidene fluoride with trifluoroethylene has been probed by ultrahigh vacuum piezoresponse force microscopy in a wide temperature range from 89 to 326 K. In dramatic contrast to the macroscopic data, the piezoresponse force microscopy local switching was nonthermally activated and, at the same time, occurring at electric fields significantly lower than the intrinsic switching threshold. A "cold-field'' defect-mediated extrinsic switching is shown to be an adequate scenario describing this peculiar switching behavior. The extrinsic character of the observed polarization reversal suggests that there is no fundamental bar for lowering the coercive field in ferroelectric polymer nanostructures, which is of importance for their applications in functional electronics.

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Type
research article
DOI
10.1103/PhysRevLett.108.027603
Web of Science ID

WOS:000298991400027

Author(s)
Stolichnov, Igor  
Maksymovych, Peter
Mikheev, Evgeny
Kalinin, Sergei V.
Tagantsev, Alexander K.
Setter, Nava  
Date Issued

2012

Publisher

American Physical Society

Published in
Physical Review Letters
Volume

108

Article Number

027603

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LC  
Available on Infoscience
February 9, 2012
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/77631
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