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research article

The origin of antiferroelectricity in PbZrO3

Tagantsev, A. K.  
•
Vaideeswaran, K.
•
Vakhrushev, S. B.
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2013
Nature Communications

Antiferroelectrics are essential ingredients for the widely applied piezoelectric and ferroelectric materials: the most common ferroelectric, lead zirconate titanate is an alloy of the ferroelectric lead titanate and the antiferroelectric lead zirconate. Antiferroelectrics themselves are useful in large digital displacement transducers and energy-storage capacitors. Despite their technological importance, the reason why materials become antiferroelectric has remained allusive since their first discovery. Here we report the results of a study on the lattice dynamics of the antiferroelectric lead zirconate using inelastic and diffuse X-ray scattering techniques and the Brillouin light scattering. The analysis of the results reveals that the antiferroelectric state is a 'missed' incommensurate phase, and that the paraelectric to antiferroelectric phase transition is driven by the softening of a single lattice mode via flexoelectric coupling. These findings resolve the mystery of the origin of antiferroelectricity in lead zirconate and suggest an approach to the treatment of complex phase transitions in ferroics.

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Type
research article
DOI
10.1038/ncomms3229
Web of Science ID

WOS:000323717900009

Author(s)
Tagantsev, A. K.  
Vaideeswaran, K.
Vakhrushev, S. B.
Filimonov, A. V.
Burkovsky, R. G.
Shaganov, A.
Andronikova, D.
Rudskoy, A. I.
Baron, A. Q. R.
Uchiyama, H.
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Date Issued

2013

Publisher

Nature Publishing Group

Published in
Nature Communications
Volume

4

Article Number

2229

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LC  
Available on Infoscience
October 1, 2013
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/95771
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