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  4. Covalent Capture of Nitrous Oxide by N-Heterocyclic Carbenes
 
research article

Covalent Capture of Nitrous Oxide by N-Heterocyclic Carbenes

Tskhovrebov, Alexander G.  
•
Solari, Euro  
•
Wodrich, Matthew D.  
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2012
Angewandte Chemie International Edition

A good catch: N-heterocyclic carbenes (NHCs) form stable adducts with nitrous oxide (N2O) under mild reaction conditions. The adducts display unique reactivity as evidenced by an alkylation reaction which leads to a rupture of the NN bond.

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Type
research article
DOI
10.1002/anie.201106589
Web of Science ID

WOS:000298598500039

Author(s)
Tskhovrebov, Alexander G.  
Solari, Euro  
Wodrich, Matthew D.  
Scopelliti, Rosario  
Severin, Kay  
Date Issued

2012

Publisher

Wiley-Blackwell

Published in
Angewandte Chemie International Edition
Volume

51

Start page

232

End page

234

Subjects

computational chemistry

•

heterocycles

•

N-heterocyclic carbenes

•

nitrogen oxides

•

structure elucidation

•

3-Coordinate Molybdenum(Iii)

•

Density Functionals

•

Chemistry

•

Binding

•

N2O

•

Thermochemistry

•

21St-Century

•

Oxidation

•

Silanone

•

Cleavage

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCS  
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/72665
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