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review article

NMR spectroscopy probes microstructure, dynamics and doping of metal halide perovskites

Kubicki, Dominik J.  
•
Stranks, Samuel D.
•
Grey, Clare P.
Show more
August 13, 2021
Nature Reviews Chemistry

Solid-state magic-angle spinning NMR spectroscopy is a powerful technique to probe atomic-level microstructure and structural dynamics in metal halide perovskites. It can be used to measure dopant incorporation, phase segregation, halide mixing, decomposition pathways, passivation mechanisms, short-range and long-range dynamics, and other local properties. This Review describes practical aspects of recording solid-state NMR data on halide perovskites and how these afford unique insights into new compositions, dopants and passivation agents. We discuss the applicability, feasibility and limitations of H-1, C-13, N-15, N-14, Cs-133, Rb-87, K-39, Pb-207, Sn-119, Cd-113, Bi-209, In-115, F-19 and H-2 NMR in typical experimental scenarios. We highlight the pivotal complementary role of solid-state mechanosynthesis, which enables highly sensitive NMR studies by providing large quantities of high-purity materials of arbitrary complexity and of chemical shifts calculated using density functional theory. We examine the broader impact of solid-state NMR on materials research and how its evolution over seven decades has benefitted structural studies of contemporary materials such as halide perovskites. Finally, we summarize some of the open questions in perovskite optoelectronics that could be addressed using solid-state NMR. We, thereby, hope to stimulate wider use of this technique in materials and optoelectronics research.

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Type
review article
DOI
10.1038/s41570-021-00309-x
Web of Science ID

WOS:000684786700001

Author(s)
Kubicki, Dominik J.  
Stranks, Samuel D.
Grey, Clare P.
Emsley, Lyndon  
Date Issued

2021-08-13

Published in
Nature Reviews Chemistry
Volume

5

Start page

624

End page

645

Subjects

Chemistry, Multidisciplinary

•

Chemistry

•

solid-state nmr

•

nuclear-magnetic-resonance

•

methylammonium lead iodide

•

high-resolution nmr

•

solar-cells

•

hybrid perovskites

•

phase-transitions

•

cation dynamics

•

enhanced nmr

•

mechanochemical synthesis

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LRM  
FunderGrant Number

FNS

200020_178860

Available on Infoscience
August 28, 2021
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/180884
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