Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Quantum Dynamics of H-2 and D-2 Confined in Hydrate Structures as a Function of Pressure and Temperature
 
research article

Quantum Dynamics of H-2 and D-2 Confined in Hydrate Structures as a Function of Pressure and Temperature

Ranieri, Umbertoluca  
•
Koza, Michael Marek
•
Kuhs, Werner F.
Show more
January 24, 2019
Journal Of Physical Chemistry C

We present an extensive study of the quantum dynamics of molecular hydrogen trapped within the nanocavities of two hydrate structures at low temperatures, namely, clathrate structure II and filled ice structure Cl. By inelastic neutron scattering measurements, we investigate a (i) simple H-2 hydrate in clathrate structure II at ambient and high pressure and different temperatures, (ii) binary He-H-2 hydrate in clathrate structure II at high pressure and different temperatures, (iii) simple D-2 hydrate in clathrate structure II at ambient pressure and different temperatures, and (iv) simple H-2 hydrate in structure Cl at high pressure and different temperatures. Molecular quantum rotations and translations, as well as combinations of these are identified in the spectra for hydrogen molecules in the small and large cages of clathrate structure II and in the channels of structure Cl and their energy is provided.

  • Details
  • Metrics
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés