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  4. Photocatalytic Hydrogen Generation from a Visible-Light-Responsive Metal–Organic Framework System: Stability versus Activity of Molybdenum Sulfide Cocatalysts
 
research article

Photocatalytic Hydrogen Generation from a Visible-Light-Responsive Metal–Organic Framework System: Stability versus Activity of Molybdenum Sulfide Cocatalysts

Nguyen, Tu N.
•
Kampouri, Stavroula  
•
Valizadeh, Bardiya  
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September 12, 2018
ACS Applied Materials & Interfaces

We report the use of two earth abundant molybdenum sulfide-based cocatalysts, Mo(3)S(13)(2-)clusters and 1T-MoS2 nanoparticles (NPs), in combination with the visible-light active metal-organic framework (MOF) MIL-125-NH2 for the photocatalytic generation of hydrogen (H-2) from water splitting. Upon irradiation (lambda >= 420 nm), the best-performing mixtures of Mo3S132-/MIL-125-NH2 and 1T-MoS2/MIL-125-NH2 exhibit high catalytic activity, producing H-2 with evolution rates of 2094 and 1454 mu mol h(-1) g(MOF)(-1) and apparent quantum yields of 11.0 and 5.8% at 450 nm, respectively, which are among the highest values reported to date for visible-light-driven photocatalysis with MOFs. The high performance of Mo3S132- can be attributed to the good contact between these clusters and the MOF and the large number of catalytically active sites, while the high activity of 1T-MoS2 NPs is due to their high electrical conductivity leading to fast electron transfer processes. Recycling experiments revealed that although the Mo3S132-/MIL-125-NH2 slowly loses its activity, the 1T-MoS2/MIL-125-NH2 retains its activity for at least 72 h. This work indicates that earth-abundant compounds can be stable and highly catalytically active for photocatalytic water splitting, and should be considered as promising cocatalysts with new MOFs besides the traditional noble metal NPs.

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Type
research article
DOI
10.1021/acsami.8b10010
Web of Science ID

WOS:000444793000004

Author(s)
Nguyen, Tu N.
Kampouri, Stavroula  
Valizadeh, Bardiya  
Luo, Wen  
Ongari, Daniele  
Planes, Ophelie Marie  
Zuttel, Andreas  
Smit, Berend  
Stylianou, Kyriakos C.  
Kampouri, Stavroula
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Date Issued

2018-09-12

Published in
ACS Applied Materials & Interfaces
Volume

10

Issue

36

Start page

30035

End page

30039

Subjects

Nanoscience & Nanotechnology

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Materials Science, Multidisciplinary

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Science & Technology - Other Topics

•

Materials Science

•

metal-organic framework

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hydrogen

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molybdenum sulfide

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photocatalysis

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visible light

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driven h-2 production

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evolution

•

efficient

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mos2

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separation

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graphene

•

clusters

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1t-mos2

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water

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mof

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSMO  
LMER  
Available on Infoscience
December 13, 2018
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/152037
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