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  4. Kinetic and thermodynamic properties of nitrosyl iodide and nitryl iodide intermediate complexes in iodine recombination
 
research article

Kinetic and thermodynamic properties of nitrosyl iodide and nitryl iodide intermediate complexes in iodine recombination

Van den Bergh, H.  
•
Troe, J.
1976
The Journal of Chemical Physics

The recombination of I atoms after laser flash photolysis was studied in the presence of NO or NO2 at 320-450 DegK and 0-200 atm of He. The reaction proceeds in 2 stages. The 1st stage is governed by the recombination I + NO (+He) -> INO (+He) or I + NO2 (+He) -> INO2 (+He), for which the full falloff curves are derived. The 2nd stage is governed either by reaction between 2 INO (or INO2) mols., or, at higher temps., by thermal decompn. of INO (or INO2). The reaction involves the elementary steps of a typical intermediate complex mechanism of atom recombination. The rates of all of these elementary steps can be sepd. From the I + NO .dblarw. INO and I + NO2 .dblarw. INO2 equil. consts. the enthalpies of formation of INO and INO2 of DHf0298(INO) = 29.0 +- 1 kcal mole-1 and DHf0298(INO2) = 14.4 +- 1 kcal mole-1, resp., are derived.

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