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  4. Print-Light-Synthesis of Platinum Nanostructured Indium-Tin-Oxide Electrodes for Energy Research
 
research article

Print-Light-Synthesis of Platinum Nanostructured Indium-Tin-Oxide Electrodes for Energy Research

Lesch, Andreas  
2018
Advanced Materials Technologies

Print-light-synthesis is a new concept for the large-scale in situ fabrication of nanoparticles and structures on large substrates. Here, Pt nanoparticles are synthesized on indium tin oxide (ITO) coated glass slides by using combined inkjet printing and photonic curing operated under ambient conditions and with low material usage. A formulated chloroplatinic acid based ink provides stable and reproducible jetting, optimized ink–substrate interaction and fast ink drying to create well-defined thin precursor films acting as nanoreactors. The precursor loading is precisely controlled by the printing parameters. Then, a short light pulse from a Xe flash lamp fully converts the printed Pt precursor containing film into pure Pt nanoparticles. The optimum precursor coverage is ≈1 µg mm−2 Pt consuming as less as ≈50 nL mm−2 of ink. Neither reducing nor capping agents are used resulting in pure Pt nanoparticles (30 nm average size) and micrometer-size aggregates. The nanostructures are well-adhered to the ITO substrate and show a stable electrochemical performance for the oxygen reduction reaction. The fast and cost-effective process optimization in terms of ink formulation, substrate pre-treatment, inkjet printing resolution, and post-processing for the rapid fabrication of Pt nano- and microparticle-coated ITO electrodes is presented and discussed.

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Type
research article
DOI
10.1002/admt.201700201
Author(s)
Lesch, Andreas  
Date Issued

2018

Publisher

Wiley

Published in
Advanced Materials Technologies
Volume

3

Article Number

1700201

Subjects

Nanoparticles

•

Platinum

•

Inkjet Printing

•

Photonic Curing

•

Pulsed Light Sintering

•

Flash Light Irradiation

•

Print Light Synthesis

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LEPA  
Available on Infoscience
December 5, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/142658
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