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research article

Hydrophobic Meshes for Oil Spill Recovery Devices

Deng, Da
•
Prendergast, Daniel P.
•
Macfarlane, John
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2013
ACS Applied Materials & Interfaces

Widespread use of petrochemicals often leads to accidental releases in aquatic environments, occasionally with disastrous results. We have developed a hydrophobic and oleophilic mesh that separates oil from water continuously in situ via capillary action, providing a means of recovering spilt oil from surface waters. Steel mesh is dip-coated in a xylene solution of low-density polyethylene, creating a hydrophobic surface with tunable roughness and opening size. The hydrophobic mesh allows oil to pass through the openings while preventing the concomitant passage of water. A bench-top prototype demonstrated the efficacy of such an oil recovery device and allowed us to quantify the factors governing the ability of the mesh to separate oil and water. Preliminary data analysis suggested that the oleophilic openings behave somewhat like capillary tubes: the oil flux is inversely proportional to oil viscosity, and directly proportional to the size of the mesh openings. An unpinned meniscus model was found to predict the water intrusion pressure successfully, which increased as the opening size decreased. The trade-off between water intrusion and oil flow rate suggests an optimal pore size for given oil properties and sea conditions.

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Type
research article
DOI
10.1021/am302338x
Web of Science ID

WOS:000315079700041

Author(s)
Deng, Da
Prendergast, Daniel P.
Macfarlane, John
Bagatin, Roberto
Stellacci, Francesco  
Gschwend, Philip M.
Date Issued

2013

Publisher

Amer Chemical Soc

Published in
ACS Applied Materials & Interfaces
Volume

5

Issue

3

Start page

774

End page

781

Subjects

low-density polyethylene (LDPE)

•

separation

•

oil spill remediation

•

functionalized mesh

•

hydrophobic

•

oleophilic

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
SUNMIL  
Available on Infoscience
March 28, 2013
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/90753
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