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  4. The Quantum Magnetism of Individual Manganese-12-Acetate Molecular Magnets Anchored at Surfaces
 
research article

The Quantum Magnetism of Individual Manganese-12-Acetate Molecular Magnets Anchored at Surfaces

Kahle, Steffen
•
Deng, Zhitao
•
Malinowski, Nikola
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2012
Nano Letters

The high intrinsic spin and long spin relaxation time of manganese-12-acetate (Mn-12) makes it an archetypical single molecular magnet. While these characteristics have been measured on bulk samples, questions remain whether the magnetic properties replicate themselves in surface supported isolated molecules, a prerequisite for any application. Here we demonstrate that electrospray ion beam deposition facilitates grafting of intact Mn-12 molecules on metal as well as ultrathin insulating surfaces enabling submolecular resolution imaging by scanning tunneling microscopy. Using scanning tunneling spectroscopy we detect spin excitations from the magnetic ground state of the molecule at an ultrathin boron nitride decoupling layer. Our results are supported by density functional theory based calculations and establish that individual Mn-12 molecules retain their intrinsic spin on a well chosen solid support.

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Type
research article
DOI
10.1021/nl204141z
Web of Science ID

WOS:000298943100090

Author(s)
Kahle, Steffen
Deng, Zhitao
Malinowski, Nikola
Tonnoir, Charlene
Forment-Aliaga, Alicia
Thontasen, Nicha
Rinke, Gordon
Le, Duy
Turkowski, Volodymyr
Rahman, Talat S.
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Date Issued

2012

Publisher

American Chemical Society (ACS)

Published in
Nano Letters
Volume

12

Start page

518

End page

521

Subjects

Electrospray mass spectrometry

•

ion beam deposition

•

molecular magnetism

•

scanning tunneling microscopy

•

inelastic tunneling spectroscopy

•

Single

•

Mn-12

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Mn-12-Acetate

•

Excitations

•

Neutron

•

Cluster

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSEN  
Available on Infoscience
February 9, 2012
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/77635
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