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research article

Quantitative Nanoscale Absorption Mapping: A Novel Technique To Probe Optical Absorption of Two-Dimensional Materials

Negri, Marco  
•
Francaviglia, Luca  
•
Dumcenco, Dumitru  
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December 24, 2019
Nano Letters

Two-dimensional semiconductors, in particular transition metal dichalcogenides and related heterostructures, have gained increasing interest as they constitute potential new building blocks for the next generation of electronic and optoelectronic applications. In this work, we develop a novel nondestructive and noncontact technique for mapping the absorption properties of 2D materials, by taking advantage of the underlying substrate cathodoluminescence emission. We map the quantitative absorption of MoS2 and MoSe2 monolayers, obtained on sapphire and oxidized silicon, with nanoscale resolution. We extend our technique to the characterization of the absorption properties of MoS2/MoSe2 van der Waals heterostructures. We demonstrate that interlayer excitonic phenomena enhance the absorption in the UV range. Our technique also highlights the presence of defects such as grain boundaries and ad-layers. We provide measurements on the absorption of grain boundaries in monolayer MoS2 at different merging angles. We observe a higher absorption yield of randomly oriented monolayers with respect to 60° rotated monolayers. This work opens up a new possibility for characterizing the functional properties two dimensional semiconductors at the nanoscale.

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Type
research article
DOI
10.1021/acs.nanolett.9b04304
Author(s)
Negri, Marco  
Francaviglia, Luca  
Dumcenco, Dumitru  
Bosi, Matteo
Kaplan, Daniel
Swaminathan, Venkataraman
Salviati, Giancarlo
Kis, Andras
Fabbri, Filippo
Fontcuberta i Morral, Anna  
Date Issued

2019-12-24

Publisher

American Chemical Society (ACS)

Published in
Nano Letters
Volume

20

Issue

1

Start page

567

End page

576

Note

This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LMSC1  
LANES  
Available on Infoscience
January 9, 2020
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/164493
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