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research article

Scavenging Free Radicals To Preserve Enhancement and Extend Relaxation Times in NMR using Dynamic Nuclear Polarization

Miéville, Pascal  
•
Ahuja, Puneet  
•
Sarkar, Riddhiman  
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2010
Angewandte Chemie International Edition

Vitamin C for longer lifetimes: N-oxide radicals that are widely used for dynamic nuclear polarization can be reduced by scavengers such as sodium ascorbate (vitamin C) during the dissolution process, thus diminishing losses of polarization during the transfer and extending transverse and longitudinal relaxation times in NMR spectroscopy.

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Type
research article
DOI
10.1002/anie.201000934
Web of Science ID

WOS:000281316000027

Author(s)
Miéville, Pascal  
Ahuja, Puneet  
Sarkar, Riddhiman  
Jannin, Sami  
Vasos, Paul Romeo  
Gerber, Sandrine  
Mishkovsky, Mor  
Comment, Arnaud  
Gruetter, Rolf  
Ouari, Olivier
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Date Issued

2010

Publisher

Wiley-Blackwell

Published in
Angewandte Chemie International Edition
Volume

49

Start page

6182

End page

6185

Subjects

DNP

•

Scavenging

•

radical

•

polarization

•

LLS

•

LLC

•

T1

•

dynamic nuclear polarization

•

hyperpolarization

•

NMR spectroscopy

•

radicals

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

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LRMB  
LIFMET  
GR-CO  
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Available on Infoscience
July 26, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/51861
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