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  4. Fully textured monolithic perovskite/silicon tandem solar cells with 25.2% power conversion efficiency
 
research article

Fully textured monolithic perovskite/silicon tandem solar cells with 25.2% power conversion efficiency

Sahli, Florent  
•
Werner, Jérémie
•
Kamino, Brett A.
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June 11, 2018
Nature Materials

Tandem devices combining perovskite and silicon solar cells are promising candidates to achieve power conversion efficiencies above 30% at reasonable costs. State-of-the-art monolithic two-terminal perovskite/silicon tandem devices have so far featured silicon bottom cells that are polished on their front side to be compatible with the perovskite fabrication process. This concession leads to higher potential production costs, higher reflection losses and non-ideal light trapping. To tackle this issue, we developed a top cell deposition process that achieves the conformal growth of multiple compounds with controlled optoelectronic properties directly on the micrometre-sized pyramids of textured monocrystalline silicon. Tandem devices featuring a silicon heterojunction cell and a nanocrystalline silicon recombination junction demonstrate a certified steady-state efficiency of 25.2%. Our optical design yields a current density of 19.5 mA cm−2 thanks to the silicon pyramidal texture and suggests a path for the realization of 30% monolithic.

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Type
research article
DOI
10.1038/s41563-018-0115-4
Author(s)
Sahli, Florent  
Werner, Jérémie
Kamino, Brett A.
Bräuninger, Matthias  
Monnard, Raphaël
Paviet-Salomon, Bertrand
Barraud, Loris
Ding, Laura
Diaz Leon, Juan J.
Sacchetto, Davide
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Date Issued

2018-06-11

Published in
Nature Materials
Volume

17

Issue

9

Start page

820

End page

826

Subjects

Materials for devices

•

Materials for energy and catalysis

•

Materials science

•

Solar cells

•

Solar energy and photovoltaic technology

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
PV-LAB  
FunderGrant Number

Swiss federal funding

SI/501072-01

Swiss federal funding

Nano-tera.ch Synergy

FNS

CRSII5_171000

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Available on Infoscience
June 13, 2018
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/146839
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