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  4. Discrete Helmholtz model: a single layer of correlated counter-ions. Metal oxides and silica interfaces, ion-exchange and biological membranes
 
research article

Discrete Helmholtz model: a single layer of correlated counter-ions. Metal oxides and silica interfaces, ion-exchange and biological membranes

Gschwend, Gregoire C.
•
Girault, Hubert H.  
October 14, 2020
Chemical Science

The mechanism by which interfaces in solution can be polarised depends on the nature of the charge carriers. In the case of a conductor, the charge carriers are electrons and the polarisation is homogeneous in the plane of the electrode. In the case of an insulator covered by ionic moieties, the polarisation is inhomogeneous and discrete in the plane of the interface. Despite these fundamental differences, these systems are usually treated in the same theoretical framework that relies on the Poisson-Boltzmann equation for the solution side. In this perspective, we show that interfaces polarised by discrete charge distributions are rather ubiquitous and that their associated potential drop significantly differs from those of conductor-electrolyte interfaces. We show that these configurations, spanning liquid-liquid interfaces, charged silica-water interfaces, metal oxide interfaces, supercapacitors, ion-exchange membranes and even biological membranes can be uniformly treated under a common "Discrete Helmholtz" model where the discrete charges are compensated by a single layer of correlated counter-ions, thereby generating a sharp potential drop at the interface.

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Type
research article
DOI
10.1039/d0sc03748f
Web of Science ID

WOS:000575657200001

Author(s)
Gschwend, Gregoire C.
Girault, Hubert H.  
Date Issued

2020-10-14

Published in
Chemical Science
Volume

11

Issue

38

Start page

10304

End page

10312

Subjects

Chemistry, Multidisciplinary

•

Chemistry

•

electric-fields

•

dielectric-constant

•

polar liquids

•

stern layer

•

adsorption

•

dynamics

•

charge

•

water

•

surface

•

conductivity

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LEPA  
Available on Infoscience
June 19, 2021
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/178928
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