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research article

Anomalous cadmium adsorption in flow interruption experiments

Tran, Y. T.
•
Bajracharya, K.
•
Barry, D. A.  
1998
Geoderma

Adsorption of cadmium (Cd) onto fine sand was investigated using batch (static) and steady flow (dynamic) experiments at pHs of 5.5, 6.0 and 6.5. For both types of experiment, adsorption of Cd onto sand was found to increase with pH. In all experiments, greater adsorption of Cd was found in flow experiments than in batch experiments. Flow interruption was used to test whether nonequilibrium sorption occurred during transport of Cd. No concentration drop was observed immediately after the resumption of flow. Instead, for all experiments, a consistent increase in effluent concentration was observed indicating that Cd was desorbed during the interruption period. This indicates the significance of velocity on adsorption/desorption of Cd onto the sand. The amount of desorption was predicted by a transition from the dynamic to the static sorption isotherm.

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Type
research article
DOI
10.1016/S0016-7061(97)00127-4
Author(s)
Tran, Y. T.
Bajracharya, K.
Barry, D. A.  
Date Issued

1998

Published in
Geoderma
Volume

84

Issue

1-3

Start page

169

End page

184

Subjects

Cadmium adsorption

•

Flow interruption experiments

•

Static sorption isotherm

•

Laboratory soil columns

•

Displacement experiments

•

Boundary conditions

•

Sorption

•

Batch experiments

•

Isotherms

•

Transport experiments

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
ECOL  
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/221077
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