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  4. Nucleation-Limited Kinetics of GaAs Nanostructures Grown by Selective Area Epitaxy: Implications for Shape Engineering in Optoelectronics Devices
 
research article

Nucleation-Limited Kinetics of GaAs Nanostructures Grown by Selective Area Epitaxy: Implications for Shape Engineering in Optoelectronics Devices

Zendrini, Michele  
•
Dubrovskii, Vladimir
•
Rudra, Alok  
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August 13, 2024
Acs Applied Nano Materials

The growth kinetics of vertical III−V nanowires (NWs) were clarified long ago. The increasing aspect ratio of NWs results in an increase in the surface area, which, in turn, enhances the material collection. The group III adatom diffusion from the NW sidewalls to the top sustains a superlinear growth regime. In this work, we report on the growth of different GaAs nanostructures by selective area MOVPE on GaAs (111)B substrates. We show that the opening dimensions and geometry qualitatively alter the morphology and height evolution of the structures. We compare the time evolution of vertical GaAs NWs stemming from circular holes and horizontal GaAs nanomembranes (NMs) growing from one-dimensional (1D) rectangular slits on the same substrate. While NW heights grow exponentially with time, NMs surprisingly exhibit sublinear kinetics. The absence of visible atomic steps on the top facets of both NWs and NMs suggests layer-by-layer growth in the mononuclear mode. We interpret these observations within a self-consistent growth model, which links the diffusion flux of Ga adatoms to the position-and shape-dependent nucleation rate on top of NWs and NMs. Specifically, the island nucleation rate is lower on top of the NMs than that on the NWs, resulting in the total diffusion flux being directed from the top facet to the sidewalls. This gives a sublinear height evolution for the NMs. These results open innovative perspectives for shape engineering of III−V nanostructures and new avenues for the design of optoelectronics and photonic devices.

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Type
research article
DOI
10.1021/acsanm.4c02765
Author(s)
Zendrini, Michele  

EPFL

Dubrovskii, Vladimir

St Petersburg University

Rudra, Alok  

EPFL

Dede, Didem  

EPFL

Fontcuberta i Morral, Anna  

EPFL

Piazza, Valerio  

EPFL

Date Issued

2024-08-13

Publisher

American Chemical Society (ACS)

Published in
Acs Applied Nano Materials
Volume

7

Issue

16

Start page

19065

End page

19074

Subjects

SAE

•

MOVPE

•

GaAs

•

nanowires

•

growth kinetics

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LMSC1  
FunderFunding(s)Grant NumberGrant URL

Swiss National Science Foundation

CRSK-2_221120

St Petersburg University

95440344

National Center of Competence in Research Quantum Science and Technology

200021_196948

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RelationRelated workURL/DOI

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[Dataset] Nucleation-Limited Kinetics of GaAs Nanostructures Grown by Selective Area Epitaxy: Implications for Shape Engineering in Optoelectronics Devices

https://infoscience.epfl.ch/handle/20.500.14299/241758
Available on Infoscience
October 29, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/241759
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