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research article

Plasmon resonances of silver nanowires with a nonregular cross section

Martin, O.J.F.  
•
Smith, D.R.
•
Schultz, S.
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2001
Physical Review B

We investigate numerically the spectrum of plasmon resonances for metallic nanowires with a nonregular cross section, in the 20-50 nm range. We first consider the resonance spectra corresponding to nanowires whose cross sections form different simplexes. The number of resonances strongly increases when the section symmetry decreases: A cylindrical wire exhibits one resonance, whereas we observe more than five distinct resonances for a triangular particle. The spectral range covered by these different resonances becomes very large, giving to the particle-specific distinct colors. At the resonance, dramatic field enhancement is observed at the vicinity of nonregular particles, where the field amplitude can reach several hundred times that of the illumination field. This near-field enhancement corresponds to surface-enhanced Raman scattering (SERS) enhancement locally in excess of 10(12). The distance dependence of this enhancement is investigated and we show that it depends on the plasmon resonance excited in the particle, i.e., on the illumination wavelength. The average Raman enhancement for molecules distributed on the entire particle surface is also computed and discussed in the context of experiments in which large numbers of molecules are used.

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Type
research article
DOI
10.1103/PhysRevB.64.235402
Web of Science ID

WOS:000172867900118

Author(s)
Martin, O.J.F.  
Smith, D.R.
Schultz, S.
Kottmann, J.P.
Date Issued

2001

Published in
Physical Review B
Volume

64

Article Number

235402

Subjects

Enhanced Raman-Scattering

•

Discrete Dipole Approximation

•

Metallic Nanoparticles

•

Near-Field

•

Nanosphere Lithography

•

Optical-Properties

•

Molecule Detection

•

Particles

•

Clusters

•

Spectroscopy

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
NAM  
Available on Infoscience
April 11, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/66184
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