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research article

Chemical evolution of primary and secondary biomass burning aerosols during daytime and nighttime

Yazdani, Amir  
•
Takahama, Satoshi  
•
Kodros, John K.
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July 10, 2023
Atmospheric Chemistry And Physics

Primary emissions from wood and pellet stoves were aged in an atmospheric simulation chamber under daytime and nighttime conditions. The aerosol was analyzed with online aerosol mass spectrometry and offline Fourier transform infrared spectroscopy (FTIR). Measurements using the two techniques agreed reasonably well in terms of the organic aerosol (OA) mass concentration, OA V OC trends, and concentrations of biomass burning markers - lignin-like compounds and anhydrosugars. Based on aerosol mass spectrometry, around 15% of the primary organic aerosol (POA) mass underwent some form of transformation during daytime oxidation conditions after 6-10 h of atmospheric exposure. A lesser extent of transformation was observed during the nighttime oxidation. The decay of certain semi-volatile (e.g., levoglucosan) and less volatile (e.g., lignin-like) POA components was substantial during aging, highlighting the role of heterogeneous reactions and gas-particle partitioning. Lignin-like compounds were observed to degrade under both daytime and nighttime conditions, whereas anhydrosugars degraded only under daytime conditions. Among the marker mass fragments of primary biomass burning OA (bbPOA), heavy ones (higher m=z) were relatively more stable during aging. The biomass burning secondary OA (bbSOA) became more oxidized with continued aging and resembled that of aged atmospheric organic aerosols. The bbSOA formed during daytime oxidation was dominated by acids. Organonitrates were an important product of nighttime reactions in both humid and dry conditions. Our results underline the importance of changes to both the primary and secondary biomass burning aerosols during their atmospheric aging. Heavier fragments from aerosol mass spectrometry seldom used in atmospheric chemistry can be used as more stable tracers of bbPOA and, in combination with the established levoglucosan marker, can provide an indication of the extent of bbPOA aging.

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Type
research article
DOI
10.5194/acp-23-7461-2023
Web of Science ID

WOS:001026039500001

Author(s)
Yazdani, Amir  
Takahama, Satoshi  
Kodros, John K.
Paglione, Marco
Masiol, Mauro
Squizzato, Stefania
Florou, Kalliopi
Kaltsonoudis, Christos
Jorga, Spiro D.
Pandis, Spyros N.
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Date Issued

2023-07-10

Publisher

Copernicus GmbH

Published in
Atmospheric Chemistry And Physics
Volume

23

Issue

13

Start page

7461

End page

7477

Subjects

Environmental Sciences

•

Meteorology & Atmospheric Sciences

•

Environmental Sciences & Ecology

•

vapor wall-loss

•

fine-particle emissions

•

organic aerosol

•

mass-spectrometry

•

infrared-spectroscopy

•

functional-groups

•

elemental composition

•

size evolution

•

oh oxidation

•

oleic-acid

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LAPI  
Available on Infoscience
August 28, 2023
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/200244
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