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research article

Photocarrier-induced band-gap renormalization and ultrafast charge dynamics in black phosphorus

Roth, S  
•
Crepaldi, A  
•
Puppin, M  
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April 9, 2019
2D Materials

With its tunable band-gap and its unique optical and electronic properties black phosphorus (BP) opens exciting opportunities for optoelectronic nanotechnology. The band-gap extends from the visible to the mid-infrared spectral range, as a function of sample thickness and external parameters such as electric field and pressure. This, combined with the saturable absorption and in-plane anisotropic optical properties, makes BP a versatile platform for realizing polarization-sensitive photodetectors and absorbers. Although its near-equilibrium properties have been intensively studied, the development of efficient ultrafast optical devices requires detailed knowledge of the temporal dynamics of the photoexcited hot-carriers. Here we address the electronic response of BP to an ultrafast laser excitation, by means of time-and angle-resolved photoelectron spectroscopy. Following the optical excitation, we directly observe a shift of the valence band (VB) position, indicative of band-gap renormalization (BGR). Our data also show that the hole population in the VB relaxes with a characteristic time tau(VB) = 10.2 +/- 1.0 ps, while the lifetime of the electrons accumulated at the minimum of the conduction band is tau(CB) = 1.9 +/- 0.2 ps. The experimental results are well reproduced by ab initio calculations of the out-of-equilibrium electronic properties. Our study sets the reference for the ultrafast carrier dynamics in BP and demonstrates the material's ultrafast BGR, which is promising for optoelectronic switches.

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Type
research article
DOI
10.1088/2053-1583/ab1216
Web of Science ID

WOS:000464059700001

Author(s)
Roth, S  
Crepaldi, A  
Puppin, M  
Gatti, G  
Bugini, D
Grimaldi, I
Barrilot, T R
Arrell, C A
Frassetto, F
Poletto, L
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Date Issued

2019-04-09

Published in
2D Materials
Volume

6

Issue

3

Article Number

031001

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSU  
FunderGrant Number

FNS-NCCR

MUST

FNS

407040-154056

Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/162714
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