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research article

Ultrathin liquid sheets: water gets in shape for VUV absorption

Knurr, Jonas
•
Hemberger, Patrick
•
Ascher, Patrick
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February 3, 2025
Physical Chemistry Chemical Physics

We present absorption spectra of thin, free-flowing liquid sheets in the vacuum ultraviolet energy range using a gas-squeezed liquid jet. Compared to liquid flow cells, operation without transmission windows eliminates restrictions on the energy range. The temperature of the water sheet is estimated at 0 +/- 3 degrees C, at the verge of the supercooled regime. By adjusting flow conditions in situ, we recorded absorption spectra at water sheet thicknesses ranging from 20 to 50 nm. We show that the absorption spectra of thin jets contain significant contributions from interference effects that need to be deconvoluted from spectral contributions due to the electronic structure. We employ a Fresnel propagation model to model the spectral changes and understand the impact of thickness variations and thin film interference. This opens the door for the investigation of solvation, interface, and similar effects by recording valence band spectra.

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Type
research article
DOI
10.1039/d4cp04619f
Web of Science ID

WOS:001428587300001

PubMed ID

39991904

Author(s)
Knurr, Jonas

Swiss Federal Institutes of Technology Domain

Hemberger, Patrick

Swiss Federal Institutes of Technology Domain

Ascher, Patrick

Swiss Federal Institutes of Technology Domain

Augustin, Sven

Swiss Federal Institutes of Technology Domain

Hoffman, David J.

Stanford University

Knopp, Gregor

Swiss Federal Institutes of Technology Domain

Menzi, Samuel

Swiss Federal Institutes of Technology Domain

Sun, Zhibin

Swiss Federal Institutes of Technology Domain

Tiefenbacher, Simon

Swiss Federal Institutes of Technology Domain

Wetter, Reto

Swiss Federal Institutes of Technology Domain

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Date Issued

2025-02-03

Publisher

ROYAL SOC CHEMISTRY

Published in
Physical Chemistry Chemical Physics
Subjects

Science & Technology

•

Physical Sciences

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LUXS  
FunderFunding(s)Grant NumberGrant URL

United States Department of Energy (DOE)

ERA-NET + EJP

Swiss National Science Foundation (SNSF)

DE-AC02-76SF00515

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Available on Infoscience
March 5, 2025
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/247405
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