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research article

Thermal origin of quasilocalized excitations in glasses

Ji, Wencheng  
•
de Geus, Tom W. J.  
•
Popovic, Marko  
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December 4, 2020
Physical Review E

Key aspects of glasses are controlled by the presence of excitations in which a group of particles can rearrange. Surprisingly, recent observations indicate that their density is dramatically reduced and their size decreases as the temperature of the supercooled liquid is lowered. Some theories predict these excitations to cause a gap in the spectrum of quasilocalized modes of the Hessian that grows upon cooling, while others predict a pseudogap D-L (omega) similar to omega(alpha). To unify these views and observations, we generate glassy configurations of controlled gap magnitude w e at temperature T = 0, using so-called breathing particles, and study how such gapped states respond to thermal fluctuations. We find that (i) the gap always fills up at finite T with D-L (omega) approximate to A(4)(T) omega(4) and A(4) similar to exp(-E-a/T) at low T, (ii) E-a rapidly grows with omega(c), in reasonable agreement with a simple scaling prediction E-a similar to omega(4)(c) and (iii) at larger omega(c) excitations involve fewer particles, as we rationalize, and eventually become stringlike. We propose an interpretation of mean-field theories of the glass transition, in which the modes beyond the gap act as an excitation reservoir, from which a pseudogap distribution is populated with its magnitude rapidly decreasing at lower T. We discuss how this picture unifies the rarefaction as well as the decreasing size of excitations upon cooling, together with a stringlike relaxation occurring near the glass transition.

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Type
research article
DOI
10.1103/PhysRevE.102.062110
Web of Science ID

WOS:000595700200003

Author(s)
Ji, Wencheng  
de Geus, Tom W. J.  
Popovic, Marko  
Agoritsas, Elisabeth  
Wyart, Matthieu  
Date Issued

2020-12-04

Published in
Physical Review E
Volume

102

Issue

6

Article Number

062110

Subjects

Physics, Fluids & Plasmas

•

Physics, Mathematical

•

Physics

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
PCSL  
Available on Infoscience
January 1, 2021
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/174397
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