Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. EPFL thesis
  4. III-V Nitride Semiconductors Deposited At Low Temperature For Photovoltaic Applications
 
doctoral thesis

III-V Nitride Semiconductors Deposited At Low Temperature For Photovoltaic Applications

Thomet, Jonathan Emanuel  
2023

This thesis reports on the study and use of low temperature processes for the deposition of indium gallium nitride (InGaN) thin films in order to alleviate some of the present drawbacks of its monolitic deposition on silicon for photovoltaic applications. The first of these processes is plasma-enhanced chemical vapor deposition (PECVD), with which it was proven that lowering the growth rate generally improves the quality metrics of the layer characteristics (Urbach energy EU , crystallite size, resistivity). It is also observed that the InGaN bandgap (BG) follows the quadratic Vegard's law with respect to indium content XIn. The use of a time-of-flight mass spectrometer (TOFMS) allowed for a deeper analysis of the plasma dynamics, and the key importance of different factors leading to a deposition of higher quality layer is presented. In particular, this higher quality layer is achieved by promoting a stronger dissociation, by a more efficient evacuation of the plasma by-products, and by starting the plasma before injecting the precursors containing carbon. Eventually, most of the different layer characteristics and quality metrics are modeled as a function of all but one (the radio-frequency) deposition parameters with more or less accuracy, hinting towards the deposition conditions that should lead to an optimized layer. It is concluded that the optimized InGaN PECVD layer doesn't perform well enough to act as an absorber at that stage of the research. This is due to p-doping that could not be achieved, to optical properties that were not satisfactory enough, as well as crystallinity and resistivity ones. However the performances were good enough to still hold some potential for a contact application.

The second of these studied processes is physical vapor deposition (PVD) sputtering, which highlights the strong role of the pressure on the layer basic characteristics, reaches acceptable electrical performances with germanium doping but with a too high germanium content of the layer, and worse electrical performances with silicon doping but with a lower silicon content than with germanium. Epitaxy of undoped gallium nitride (GaN) on sapphire is demonstrated, but remains unstable under an increasing doping level of silicon. Increasing the indium content of the layer helps decrease the resistivity, but still to values at least two orders of magnitude greater than the standard (n)a-Si:H layer usually used for contacting the absorber. For the exact same reasons as with PECVD, but especially because p-doping could not be achieved as well, it is concluded that the optimized InGaN layer doesn't perform well enough to act as an absorber, but has acceptable characteristics for a contact application. This thesis also reports on the integration of these optimized layers in solar cell architectures as contacts. It is observed that indeed, the "barely sufficient" layer properties (be it optical, electrical or structural) doesn't improve the cell performances compared to state-of-the-art literature values. However, for each technique used and presented (undoped In/GaN by PECVD, doped GaN and undoped InGaN by PVD), an electrical power is produced by the solar cell under standard test conditions, in one case even stronger than the reference cell it is compared to. The main two issues with these contacts are their too high resistivity (decreasing the open-circuit voltage (VOC) and worsening the fill factor (FF)) and their bad selectivity.

  • Files
  • Details
  • Metrics
Type
doctoral thesis
DOI
10.5075/epfl-thesis-10249
Author(s)
Thomet, Jonathan Emanuel  
Advisors
Hessler-Wyser, Aïcha  
•
Würsch, Nicolas  
Jury

Prof. Romuald Houdré (président) ; Dr Aïcha Hessler-Wyser, Dr Nicolas Würsch (directeurs) ; Prof. Anna Fontcuberta i Morral, Prof. Thomas Nelis, Dr Gabriel Christmann (rapporteurs)

Date Issued

2023

Publisher

EPFL

Publisher place

Lausanne

Public defense year

2023-06-16

Thesis number

10249

Total of pages

316

Subjects

InGaN

•

PECVD

•

sputtering

•

silicon

•

solar cell

•

contact

•

design of experiment

•

doping

•

electron microscopy

•

TOFMS

EPFL units
PV-LAB  
Faculty
STI  
School
IMT  
Doctoral School
EDPY  
Available on Infoscience
June 5, 2023
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/198134
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés