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  4. Understanding and decoupling the role of wavelength and defects in light-induced degradation of metal-halide perovskites
 
research article

Understanding and decoupling the role of wavelength and defects in light-induced degradation of metal-halide perovskites

Hieulle, Jeremy
•
Krishna, Anurag  
•
Boziki, Ariadni
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December 1, 2023
Energy & Environmental Science

Light-induced degradation in metal halide perovskites is a major concern that can potentially hamper the commercialization of perovskite optoelectronic devices. The phenomena viz. ion migration, phase segregation, and defect intolerance are believed to be the factors behind the degradation. However, a detailed mechanistic understanding of how and why light reduces the long-term stability of perovskites is still lacking. Here, by combining multiscale characterization techniques and computational studies, we uncover the role of white light in the surface degradation of state-of-the-art FAPbI3-rich perovskite absorbers (reaching up to 22% PCE in solar cells). We unravel the degradation kinetics and found that white light triggers the chemical degradation of perovskite into secondary phases with higher work function and metallic I-V characteristics. Furthermore, we demonstrate that perovskite degradation is triggered by a combined mechanism involving both light and the presence of defects. We employ surface passivation to understand the role of defect intolerance in the degradation process. Moreover, by using filtered light we uncover the wavelength dependency of the light-induced perovskite degradation. Based on our findings, we infer some strategies for material engineering and device design that can expedite the path toward stable perovskite optoelectronic devices.|Light-induced degradation in metal halide perovskites is a major concern that can potentially hamper the commercialization of perovskite optoelectronic devices.

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Type
research article
DOI
10.1039/d3ee03511e
Web of Science ID

WOS:001111600900001

Author(s)
Hieulle, Jeremy
Krishna, Anurag  
Boziki, Ariadni
Audinot, Jean-Nicolas
Farooq, Muhammad Uzair
Machado, Joana Ferreira
Mladenovic, Marko
Phirke, Himanshu
Singh, Ajay
Wirtz, Tom
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Date Issued

2023-12-01

Publisher

Royal Soc Chemistry

Published in
Energy & Environmental Science
Volume

17

Issue

1

Start page

284

End page

295

Subjects

Physical Sciences

•

Technology

•

Life Sciences & Biomedicine

•

Suppressed Ion Migration

•

Solar-Cells

•

Nanocrystals

•

Efficiency

•

Tolerance

•

Stability

•

Exchange

•

Hole

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSPM  
LPI  
FunderGrant Number

Deutsche Forschungsgemeinschaft

11244141,11696002,12246511,13390539,14735144,14757355

Luxembourg National Research Fund (FNR)

SPP 2196

DFG

843453

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Available on Infoscience
February 19, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/204329
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