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research article

Towards optical optimization of planar monolithic perovskite/silicon-heterojunction tandem solar cells

Albrecht, Steve
•
Saliba, Michael  
•
Correa-Baena, Juan-Pablo  
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2016
Journal Of Optics

Combining inorganic-organic perovskites and crystalline silicon into a monolithic tandem solar cell has recently attracted increased attention due to the high efficiency potential of this cell architecture. Promising results with published efficiencies above 21% have been reported so far. To further increase the device performance, optical optimizations enabling device related guidelines are highly necessary. Here we experimentally show the optical influence of the ITO thickness in the interconnecting layer and fabricate an efficient monolithic tandem cell with a reduced ITO layer thickness that shows slightly improved absorption within the silicon sub-cell and a stabilized power output of 17%. Furthermore we present detailed optical simulations on experimentally relevant planar tandem stacks to give practical guidelines to reach efficiencies above 25%. By optimizing the thickness of all functional and the perovskite absorber layers, together with the optimization of the perovskite band-gap, we present a tandem stack that can yield ca 17.5 mA cm(-2) current in both sub-cells at a perovskite band-gap of 1.73 eV including losses from reflection and parasitic absorption. Assuming that the higher band-gap of the perovskite absorber directly translates into a higher open circuit voltage, the perovskite sub-cell should be able to reach a value of 1.3 V. With that, realistic efficiencies above 28% are within reach for planar monolithic tandem cells in which the thickness of the perovskite top-cell and the perovskite band-gap are highly optimized. When applying light trapping schemes such as textured surfaces and by reducing the parasitic absorption of the functional layers, for example in spiro-OMeTAD, this monolithic tandem can overcome 30% power conversion efficiency.

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Type
research article
DOI
10.1088/2040-8978/18/6/064012
Web of Science ID

WOS:000378065100016

Author(s)
Albrecht, Steve
Saliba, Michael  
Correa-Baena, Juan-Pablo  
Jaeger, Klaus
Korte, Lars
Hagfeldt, Anders  
Graetzel, Michael  
Rech, Bernd
Date Issued

2016

Publisher

Iop Publishing Ltd

Published in
Journal Of Optics
Volume

18

Issue

6

Article Number

064012

Subjects

perovskite solar cells

•

silicon heterojunction

•

monolithic tandem solar cell

•

optical simulation

•

device optimization

•

semitransparent solar cell

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
LSPM  
Available on Infoscience
July 19, 2016
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/127617
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