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research article

Bubble evolution on a vertical electrode under extreme current densities

Wüthrich, Rolf
•
Comninellis, Christos  
•
Bleuler, Hannes  
2005
Electrochimica Acta

Under gas evolution, the current voltage characteristics of an electrochemical cell are strongly affected by the presence of growing bubbles. At high current densities, the evolution of the bubbles becomes the rate limiting step of the electrochemical process. The knowledge of the amount of bubbles shadowing the active electrochemical surface of the working electrode has many important practical consequences. This contribution presents a model describing qualitatively the evolution of the bubbles evolving on the working electrode. The theoretical investigations indicate that one of the mechanisms influencing the fraction of active electrode surface is their ability to coalesce or not.

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Type
research article
DOI
10.1016/j.electacta.2004.12.052
Web of Science ID

WOS:000232344100049

Author(s)
Wüthrich, Rolf
Comninellis, Christos  
Bleuler, Hannes  
Date Issued

2005

Published in
Electrochimica Acta
Volume

50

Issue

25-26

Start page

5242

End page

5246

Subjects

Bubble evolution

•

Electrode effects

•

Anode effect

•

SACE

•

[SACE]

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GGEC  
LSRO  
Available on Infoscience
June 2, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/230288
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