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  4. Revealing fundamentals of charge extraction in photovoltaic devices through potentiostatic photoluminescence imaging
 
research article

Revealing fundamentals of charge extraction in photovoltaic devices through potentiostatic photoluminescence imaging

Wagner, Lukas
•
Schygulla, Patrick
•
Herterich, Jan Philipp
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July 6, 2022
Matter

The photocurrent density-voltage (J(V)) curve is the fundamental characteristic to assess opto-electronic devices, in particular solar cells. However, it only yields information on the performance inte-grated over the entire active device area. Here, a method to deter-mine spatially resolved photocurrent images by voltage-dependent photoluminescence microscopy is derived from basic principles. The opportunities and limitations of the approach are studied by the investigation of III-V and perovskite solar cells. This approach allows the real-time assessment of the microscopically resolved local J(V) curve and the steady-state Jsc as well as transient effects. In addi-tion, the measurement contains information on local charge extrac-tion and interfacial recombination. This facilitates the identification of regions of non-ideal charge extraction and enables linking these to the processing conditions. The proposed technique highlights that, combined with potentiostatic measurements, luminescence microscopy can be a powerful tool for the assessment of perfor-mance losses and the improvement of solar cells.

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Type
research article
DOI
10.1016/j.matt.2022.05.024
Web of Science ID

WOS:000829616700002

Author(s)
Wagner, Lukas
Schygulla, Patrick
Herterich, Jan Philipp
Elshamy, Mohamed
Bogachuk, Dmitry
Zouhair, Salma
Mastroianni, Simone
Wuerfel, Uli
Liu, Yuhang  
Zakeeruddin, Shaik M.  
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Date Issued

2022-07-06

Publisher

ELSEVIER

Published in
Matter
Volume

5

Issue

7

Subjects

Materials Science, Multidisciplinary

•

Materials Science

•

circuit current-density

•

solar-cells

•

series resistance

•

degradation

•

hysteresis

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
August 15, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/190076
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