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research article

New Insight into the Formation of Hybrid Perovskite Nanowires via Structure Directing Adducts

Petrov, Andrey A.
•
Pellet, Norman  
•
Seo, Ji-Youn  
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2017
Chemistry Of Materials

We report a facile preparation approach of MAPbBr(3), MAPbCl(3), or FAPbBr(3) (where MA = CH3NH3+ and FA = CH(NH2)(2)(+)) perovskite nanowires via sequential synthesis of MAPbI(3) and FAPbI(3) nanowires with chemically controlled composition and morphologies followed by an exchange of halide anions. The nanowires formation sequence includes intermediate phases such as MAI-PbI2-DMF and FAIPbIrDMF (DMF = dimethylformamide) acting as structure directing agent. The 1D shape of the adduct is preserved during the conversion to perovskite. The adducts play the role of key precursors controlling the final product morphology. Systematic investigations of the observed phase transformations and morphology features on multiple length scales revealed the effectiveness of the suggested synthetic route utilizing an original pseudomorph formation mechanism of the 1D structures to produce partly oriented films and textured layers of the nanowires via only a few experimental steps.

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Type
research article
DOI
10.1021/acs.chemmater.6b03965
Web of Science ID

WOS:000392891700016

Author(s)
Petrov, Andrey A.
Pellet, Norman  
Seo, Ji-Youn  
Belich, Nikolai A.
Kovalev, Dmitriy Yu.
Shevelkov, Andrei V.
Goodilin, Eugene A.
Zakeeruddin, Shaik M.  
Tarasov, Alexey B.
Graetzel, Michael  
Date Issued

2017

Publisher

American Chemical Society

Published in
Chemistry Of Materials
Volume

29

Issue

2

Start page

587

End page

594

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
March 27, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/135940
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