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research article

Light trapping in solar cells: can periodic beat random?

Battaglia, Corsin  
•
Hsu, Ching-Mei
•
Söderström, Karin  
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2012
ACS Nano

Theory predicts that periodic photonic nanostructures should outperform their random counterparts in trapping light in solar cells. However, the current certified world-record conversion efficiency for amorphous silicon thin-film solar cells, which strongly rely on light trapping, was achieved on the random pyramidal morphology of transparent zinc oxide electrodes. Based on insights from waveguide theory, we develop tailored periodic arrays of nanocavities on glass fabricated by nanosphere lithography, which enable a cell with a remarkable short-circuit current density of 17.1 mA/cm(2) and a high initial efficiency of 10.9%. A direct comparison with a cell deposited on the random pyramidal morphology of state-of-the-art zinc oxide electrodes, replicated onto glass using nanoimprint lithography, demonstrates unambiguously that periodic structures rival random textures.

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Type
research article
DOI
10.1021/nn300287j
Author(s)
Battaglia, Corsin  
Hsu, Ching-Mei
Söderström, Karin  
Escarré, Jordi
Haug, Franz-Josef  
Charrière, Mathieu
Boccard, Mathieu  
Despeisse, Matthieu  
Alexander, Duncan T. L.  
Cantoni, Marco  
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Date Issued

2012

Published in
ACS Nano
Volume

6

Issue

3

Start page

2790

End page

7

Subjects

photovoltaics

•

solar cells

•

light trapping

•

guided modes

•

Yablonovitch limit

•

amorphous silicon

•

nanoimprint lithography

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nanosphere lithography

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Silver Back Reflector

•

Fundamental Limit

•

Absorption

•

Lithography

•

Arrays

•

Oxide

Note

IMT-NE Number: 641

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
PV-LAB  
CIME  
Available on Infoscience
May 14, 2012
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/80306
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