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research article

Order-disorder type of Peierls instability in BaVS3

Ilakovac, Vita
•
Girard, Adrien
•
Baledent, Victor
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January 14, 2021
Physical Review B

Lattice dynamics of low-dimensional BaVS3 is reported across the metal-insulator Peierls transition occurring at T-P = 69 K using a combination of the thermal diffuse scattering of x rays, inelastic x-ray scattering, and density-functional theory calculations. The nondetection of a Kohn anomaly points to a unique situation of an order-disorder Peierls instability with a quasielastic critical scattering which has been fully characterized. These observations are discussed in the scope of a Peierls instability dominated by strong electron-phonon coupling and/or nonadiabatic effects.

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