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  4. Influence of Iodide Concentration on the Efficiency and Stability of Dye-Sensitized Solar Cell Containing Non-Volatile Electrolyte
 
research article

Influence of Iodide Concentration on the Efficiency and Stability of Dye-Sensitized Solar Cell Containing Non-Volatile Electrolyte

Zhang, Z. P.  
•
Ito, S.  
•
Moser, J. E.  
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2009
ChemPhysChem

Dye-sensitized solar cells based on nanocrystalline TiO2 have been fabricated with an amphiphilic ruthenium sensitizer NaRu(4-carboxylic acid-4'-carboxylate) (4,4'-dinonyl-2,2'-bipyridine)(NCS)2, coded as Z-907Na, and a series of non-volatile 3-methoxyproprionitrile (MPN)-based electrolytes with different concentration of 1-methyl-3-propylimidazolium iodide (PMII). The short-circuit photocurrent density increases with increasing iodide concentration until at 1.5M practically quantitative dye regeneration is achieved as proved by time-resolved laser experiments. Devices containing 1.0M PMII electrolyte show excellent stability during long-time thermal aging at 80 degrees C and under light soaking at 60 degrees C.

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Type
research article
DOI
10.1002/cphc.200900199
Web of Science ID

WOS:000268817800018

Author(s)
Zhang, Z. P.  
Ito, S.  
Moser, J. E.  
Zakeeruddin, S. M.  
Gratzel, M.  
Date Issued

2009

Publisher

Wiley-Blackwell

Published in
ChemPhysChem
Volume

10

Issue

11

Start page

1834

End page

1838

Subjects

dyes/pigments

•

energy conversion

•

iodide concentration

•

semiconductors

•

stability

•

Conversion Efficiency

•

Charge-Transport

•

Ionic Liquid

•

Tio2

•

Performance

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
GR-MO  
Available on Infoscience
December 23, 2009
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/44963
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