Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Absorption spectroscopy of adenine, 9-methyladenine, and 2-aminopurine in helium nanodroplets
 
research article

Absorption spectroscopy of adenine, 9-methyladenine, and 2-aminopurine in helium nanodroplets

Smolarek, Szymon
•
Rijs, Anouk M.
•
Buma, Wybren Jan
Show more
2010
Physical Chemistry Chemical Physics

High-resolution absorption spectra of adenine, 9-methyladenine and 2-aminopurine in helium nanodroplets have been recorded. In contrast to molecular beam experiments, large variations in linewidths are observed for adenine and 9-methyladenine. At the same time, the spectrum of 2-aminopurine remains sharp upon solvation in helium droplets. The line broadening observed for adenine and 9-methyladenine is attributed to a significant decrease of the lifetime of the 1Lb(pp*) state and of 1np* levels vibronically coupled to this state. The origin of the lifetime reduction is argued to be related to the increased accessibility of the 1np*/1Lb(pp*) conical intersection upon solvation of these molecules in liquid helium.

  • Files
  • Details
  • Metrics
Type
research article
DOI
10.1039/C0CP00746C
Web of Science ID

WOS:000284776700005

Author(s)
Smolarek, Szymon
Rijs, Anouk M.
Buma, Wybren Jan
Drabbels, Marcel  
Date Issued

2010

Publisher

Royal Society of Chemistry

Published in
Physical Chemistry Chemical Physics
Volume

12

Article Number

15600

Subjects

adenine

•

spectroscopy

•

excited state dynamics

•

helium nanodroplets

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCPM  
Available on Infoscience
June 29, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/51378
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés