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  4. Energy and Hole Transfer between Dyes Attached to Titania in Cosensitized Dye-Sensitized Solar Cells
 
research article

Energy and Hole Transfer between Dyes Attached to Titania in Cosensitized Dye-Sensitized Solar Cells

Hardin, Brian E.
•
Sellinger, Alan
•
Moehl, Thomas  
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2011
Journal of the American Chemical Society

Cosensitization of broadly absorbing ruthenium metal complex dyes with highly absorptive near-infrared (NIR) organic dyes is a clear pathway to increase near-infrared light harvesting in liquid- based dye-sensitized solar cells (DSCs). In cosensitized DSCs, dyes are intimately mixed, and intermolecular charge and energy transfer processes play an important role in device performance. Here, we demonstrate that an organic NIR dye incapable of hole regeneration is able to produce photocurrent via intermolecular energy transfer with an average excitation transfer efficiency of over 25% when cosensitized with a metal complex sensitizing dye (SD). We also show that intermolecular hole transfer from the SD to NIR dye is a competitive process with dye regeneration, reducing the internal quantum efficiency and the electron lifetime of the DSC. This work demonstrates the general feasibility of using energy transfer to boost light harvesting from 700 to 800 nm and also highlights a key challenge for developing highly efficient cosensitized dye-sensitized solar cells.

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Type
research article
DOI
10.1021/ja2042172
Web of Science ID

WOS:000293149800051

Author(s)
Hardin, Brian E.
Sellinger, Alan
Moehl, Thomas  
Humphry-Baker, Robin  
Moser, Jacques-E.  
Wang, Peng  
Zakeeruddin, Shaik M.  
Grätzel, Michael  
Mcgehee, Michael D.
Date Issued

2011

Published in
Journal of the American Chemical Society
Volume

133

Issue

27

Start page

10662

End page

10667

Subjects

Nanocrystalline Tio2 Films

•

Impedance Spectroscopy

•

Liquid-Electrolyte

•

Organic-Dyes

•

Relay Dyes

•

Efficiency

•

Cyanine

•

Conversion

•

Injection

•

Light

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GR-MO  
LPI  
Available on Infoscience
July 7, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/69490
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