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  4. Double Layer Composite Electrode Strategy for Efficient Perovskite Solar Cells with Excellent Reverse-Bias Stability
 
research article

Double Layer Composite Electrode Strategy for Efficient Perovskite Solar Cells with Excellent Reverse-Bias Stability

Jiang, Chaofan
•
Zhou, Junjie
•
Li, Hang
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December 1, 2023
Nano-Micro Letters

Perovskite solar cells (PSCs) have become the representatives of next generation of photovoltaics; nevertheless, their stability is insufficient for large scale deployment, particularly the reverse bias stability. Here, we propose a transparent conducting oxide (TCO) and low-cost metal composite electrode to improve the stability of PSCs without sacrificing the efficiency. The TCO can block ion migrations and chemical reactions between the metal and perovskite, while the metal greatly enhances the conductivity of the composite electrode. As a result, composite electrode-PSCs achieved a power conversion efficiency (PCE) of 23.7% (certified 23.2%) and exhibited excellent stability, maintaining 95% of the initial PCE when applying a reverse bias of 4.0 V for 60 s and over 92% of the initial PCE after 1000 h continuous light soaking. This composite electrode strategy can be extended to different combinations of TCOs and metals. It opens a new avenue for improving the stability of PSCs.

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Type
research article
DOI
10.1007/s40820-022-00985-4
Web of Science ID

WOS:000898867500001

Author(s)
Jiang, Chaofan
Zhou, Junjie
Li, Hang
Tan, Liguo
Li, Minghao
Tress, Wolfgang
Ding, Liming
Graetzel, Michael  
Yi, Chenyi
Date Issued

2023-12-01

Published in
Nano-Micro Letters
Volume

15

Issue

1

Start page

12

Subjects

Nanoscience & Nanotechnology

•

Materials Science, Multidisciplinary

•

Physics, Applied

•

Science & Technology - Other Topics

•

Materials Science

•

Physics

•

composite electrode

•

perovskite solar cells

•

stability

•

reverse bias

•

characterization

•

induced degradation

•

light-soaking

•

voltage

•

cu

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
RelationURL/DOI

IsReviewedBy

https://infoscience.epfl.ch/record/301014?ln=en
Available on Infoscience
January 16, 2023
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/193844
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