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  4. Direct Observation of Shallow Trap States in Thermal Equilibrium with Band‐Edge Excitons in Strongly Confined CsPbBr 3 Perovskite Nanoplatelets
 
research article

Direct Observation of Shallow Trap States in Thermal Equilibrium with Band‐Edge Excitons in Strongly Confined CsPbBr 3 Perovskite Nanoplatelets

Socie, Etienne Christophe  
•
De Carvalho Vale, Brener Rodrigo  
•
Burgos Caminal, Andrés  
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2021
Advanced Optical Materials

Lead halide perovskites exhibit great potential for light-emitting devices. Enhanced photoluminescence (PL) is obtained in perovskite materials of reduced dimensionalities due to the large exciton binding energy. However, as the nanocrystal size is reduced, the surface-to-volume ratio increases, leading to an abundance of surface defects. Here, a fast PL decay, 3–10 ps, is observed in quasi-1D CsPbBr3 perovskite nanoplatelets using broadband fluorescence upconversion spectroscopy. This decay is attributed to revers- ible trapping of band-edge excitons into dark states that lie close to the band edge. A simplified model is proposed to further confirm the presence of shallow traps and to fit the data obtained by ultrafast spectroscopy for mul- tiple samples. Finally, the presence of deep trap states in aged nanoplatelets is revealed, likely arising from desorption of the organic capping ligands from the surface. Exciton trapping into these states is slower, 20–30 ps, but leads to a decrease in the photoluminescence quantum yield. These results may not only explain the extended luminescence lifetimes that have been reported for perovskite nanocrystals but also demonstrate the potential of combining ultrafast transient absorption and fluorescence up-conversion to obtain a full description of the spectroscopic properties of the material.

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Type
research article
DOI
10.1002/adom.202001308
Author(s)
Socie, Etienne Christophe  
De Carvalho Vale, Brener Rodrigo  
Burgos Caminal, Andrés  
Moser, Jacques-Edouard  
Date Issued

2021

Published in
Advanced Optical Materials
Volume

9

Issue

1

Start page

2001308 (1

End page
Subjects

Cesium lead bromide perovskite

•

Exciton trapping

•

Fluorescence up-conversion spectroscopy

•

Nanoparticle aging

•

Shallow trap states

•

Strongly confined nanoplatelets

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GR-MO  
FunderGrant Number

FNS

200021_175729

RelationURL/DOI

IsSupplementedBy

https://infoscience.epfl.ch/record/290012?ln=fr

IsSupplementedBy

10.5281/zenodo.5018380
Available on Infoscience
November 10, 2020
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/173320
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