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  4. Broadband excitation in solid-state NMR of paramagnetic samples using Delays Alternating with Nutation for Tailored Excitation ('Para-DANTE')
 
research article

Broadband excitation in solid-state NMR of paramagnetic samples using Delays Alternating with Nutation for Tailored Excitation ('Para-DANTE')

Carnevale, Diego  
•
Vitzthum, Veronika  
•
Lafon, Olivier
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2012
Chemical Physics Letters

This Letter shows that interleaved sequences of short pulses in the manner of 'Delays Alternating with Nutation for Tailored Excitation' (DANTE) with N = 1,2,3 . . . equidistant pulses per rotor period extending over K rotor periods can be used to excite, invert or refocus a large number of spinning sidebands of spin-1/2 nuclei in paramagnetic samples where hyperfine couplings lead to very broad spectra that extend over more than 1 MHz. The breadth of the response is maintained for rf-field amplitudes as low as 30 kHz since it results from cumulative effects of individual pulses with very short durations.

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Type
research article
DOI
10.1016/j.cplett.2012.09.056
Web of Science ID

WOS:000310772300015

Author(s)
Carnevale, Diego  
Vitzthum, Veronika  
Lafon, Olivier
Trebosc, Julien
Amoureux, Jean-Paul
Bodenhausen, Geoffrey  
Date Issued

2012

Publisher

Elsevier

Published in
Chemical Physics Letters
Volume

553

Start page

68

End page

76

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LRMB  
Available on Infoscience
March 21, 2013
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/90507
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