Laser powder bed fusion (LPBF) as an additive manufacturing (AM) technology has emerged as a powerful platform for producing multi-material metallic structures. The main drawbacks of using metallic powders for multi-material printing are related to technical issues (i.e. powder contamination reducing the reusability of the powder) and interfacial defects. This paper attempts to demonstrate the advantages of using a combination of metallic powders and thin foils for printing light titanium-aluminum multi-material structures. An AlSi12 powder was printed using the conventional LPBF process and the behavior of the second material feedstock was investigated using both Ti6Al4V powders and foils. The printing process was simulated numerically using a finite element model (FEM), and characterized experimentally through operando X-Ray diffraction (XRD). For the powder-powder combination, cracking near the interface between the two alloys was considered as a combined effect of residual stresses and the presence of brittle intermetallic compounds (IMCs); both were investigated using nanoindentation. Replacing the Ti6Al4V powder by a foil resulted in a thinner layer of Ti-Al IMCs near the interface, and eliminated the large interfacial cracks. The results from FEM and CALPHAD thermodynamic simulations, supported by operando XRD, indicated that the increased thermal conductivity of the foil, compared to powders, led to heat transfer within the foil and to the underlying LPBF structure, prior to local melting. The new thermal regime produced a flawless interface between Ti6Al4V and AlSi12, due to reduced residual stresses in the plane normal to the building direction, and lower volumes of brittle IMCs. It is concluded that using foils instead of powders mitigates cracking and enhances microstructures near the interface, due to changes in thermal regime and alloys mixing patterns.