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  4. Bandgap engineering of indium gallium nitride layers grown by plasma-enhanced chemical vapor deposition
 
research article

Bandgap engineering of indium gallium nitride layers grown by plasma-enhanced chemical vapor deposition

Thomet, Jonathan Emanuel  
•
Singh, Aman Kamlesh
•
Roueche, Melanie Nelly  
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December 1, 2022
Journal Of Vacuum Science & Technology A

This paper reports on the fabrication of In xGa 1 - xN (InGaN) layers with various compositions ranging from InN to GaN using a cost-effective low-temperature plasma-enhanced chemical vapor deposition (PECVD) method and analyzes the influence of deposition parameters on the resulting films. Single-phase nanocrystalline InGaN films with crystallite size up to 30 nm are produced with deposition temperatures in the range of 180-250 ? using the precursors trimethylgallium, trimethylindium, hydrogen, nitrogen, and ammonia in a parallel-plate type RF-PECVD reactor. It is found that growth rate is a primary determinant of crystallinity, with rates below 6 nm/min producing the most crystalline films across a range of several compositions. Increasing In content leads to a decrease in the optical bandgap, following Vegard's law, with bowing being more pronounced at higher growth rates. Significant free-carrier absorption is observed in In-rich films, suggesting that the highly measured optical bandgap (about 1.7 eV) is due to the Burstein-Moss shift. (C) 2022 Author(s).

  • Details
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Type
research article
DOI
10.1116/6.0002039
Web of Science ID

WOS:000880128900001

Author(s)
Thomet, Jonathan Emanuel  
Singh, Aman Kamlesh
Roueche, Melanie Nelly  
Toggwyler, Nils  
Haug, Franz-Josef  
Christmann, Gabriel
Nicolay, Sylvain
Ballif, Christophe  
Wyrsch, Nicolas  
Hessler-Wyser, Aicha  
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Date Issued

2022-12-01

Published in
Journal Of Vacuum Science & Technology A
Volume

40

Issue

6

Article Number

063102

Subjects

Materials Science, Coatings & Films

•

Physics, Applied

•

Materials Science

•

Physics

•

molecular-beam epitaxy

•

amorphous gan

•

ingan

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crystalline

•

films

•

size

•

inn

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
PV-LAB  
RelationURL/DOI

IsSupplementedBy

https://infoscience.epfl.ch/record/307263

IsSupplementedBy

https://infoscience.epfl.ch/record/309572

IsSupplementedBy

https://infoscience.epfl.ch/record/309573
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Available on Infoscience
November 21, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/192403
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