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  4. Micro-addition of Fe in highly alloyed Cu-Ti alloys to improve both formability and strength
 
research article

Micro-addition of Fe in highly alloyed Cu-Ti alloys to improve both formability and strength

Rouxel, B.
•
Cayron, Cyril  
•
Bornand, Julien
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January 1, 2022
Materials & Design

Cu-Be alloys provide excellent electrical and mechanical properties, but present serious health hazards during manufacturing. Among alternative alloys, the Cu-Ti system has the highest yield strength; however, Ti cannot be easily solutionized at concentrations above 4 wt%, resulting in a relatively low formability. In this study, Cu-xTi-yFe (x = 3, 5, 6 wt% and y = 0, 0.3 wt%) alloys were studied after both solution-annealing and age-hardening through mechanical testing and microstructure analysis. Micro-additions of Fe kept high concentration of Ti in solid solution (up to 6 wt%) after water quenching and suppressed the classical "wave-like" early-stage precipitation. Instead, a new dispersion of nano precipitates was observed. This behavior results in doubling the ductility in the solution annealed state (up to 48% elongation), together with maintaining a very high strength after ageing (up to 975 MPa) from precipitation of metastable nano alpha-Cu4Ti. This study shows that Fe micro-additions, when combined with a higher amounts of Ti (6 wt%), enables the production of Cu-based alloys combining high formability and strength, providing an excellent alternative to Cu-Be in mechanical applications. (C) 2021 Published by Elsevier Ltd.

  • Details
  • Metrics
Type
research article
DOI
10.1016/j.matdes.2021.110340
Web of Science ID

WOS:000737076300005

Author(s)
Rouxel, B.
Cayron, Cyril  
Bornand, Julien
Sanders, Paul
Loge, Roland E.  
Date Issued

2022-01-01

Publisher

ELSEVIER SCI LTD

Published in
Materials & Design
Volume

213

Article Number

110340

Subjects

Materials Science, Multidisciplinary

•

Materials Science

•

cu-ti alloys

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high-strength copper alloy

•

spinodal decomposition

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precipitation strengthening

•

phase transformation

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alternative alloys to cu-be

•

prior cold work

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mechanical-properties

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precipitation behavior

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aging characteristics

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heat-treatment

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x-ray

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microstructure

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ni

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conductivity

•

deformation

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LMTM  
Available on Infoscience
January 31, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/184916
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